题目：Electrochemical N‒H Methylsulfoxidation of Sulfoximines with DMSO

作者：Qing-Ru Zhu (朱清茹, 2022级研究生), Gen Liu, Yongxiang Wang, Zhubing Xiao, Hui Gao,*(高慧) and Pei-Long Wang*(王培龙)

单位：Key Laboratory of Green and Precise Synthetic Chemistry and Applications, Ministry of Education; Anhui Provincial Key Laboratory of Synthetic Chemistry and Applications; College of Chemistry and Materials Science, Huaibei Normal University, Huaibei, Anhui 235000, China

摘要：The N‒H methylsulfoxidation of sulfoximines using DMSO as a methylsulfinyl source, induced by electrochemistry, has been developed. This method is the first example of an electrochemical reaction in which DMSO serves as a methylsulfinyl source. Unlike previous electrochemical reactions involving DMSO as a substrate, which exclusively proceed via radical mechanisms, this reaction follows an S-cation pathway. A wide range of N-methylsulfinyl sulfoximines were successfully obtained.

影响因子：5.5

分区情况：一区

年、卷、页：2025, 43, 897-904

链接：https://onlinelibrary.wiley.com/doi/10.1002/cjoc.202401029

(文、图:王培龙 /  审核:韩满意 /  审校:曹静 / 终审:杨振兴)