题目：Electron Donor-Acceptor Complex Enabled Cyclization/Sulfonylation Cascade of N-Heterocycles with Thianthrenium Salts

作者: Zhengjun He, Zhi Li, Shuo Lai, and Hongji Li*

单位：Key Laboratory of Green and Precise Synthetic Chemistry and Applications, Ministry of Education, School of Chemistry and Materials Science, Huaibei Normal University, Huaibei, Anhui 235000, P. R. China

摘要：We report a visible light-promoted cyclization/sulfonylation cascade of N-heterocycles with thianthrenium salts using DABSO as the SO₂ surrogate. This method features excellent functional group tolerance, wide substrate scope and late-stage elaboration of bioactive relevant molecules. Mechanistic investigations reveal that the photoactive electron donor−acceptor (EDA) complexes between thianthrenium salts and DABCO are capable of the generation of aryl radicals which induces the following SO₂ insertion by attacking DABSO, thus triggering the key radical cyclization step.

影响因子：5.2

分区情况：一区

链接：https://doi.org/10.1021/acs.orglett.4c02307