【学术论文】李洪基教授、王培龙副教授在Green Chemistry上发表论文
题目:Electrochemical N(sp2)–H/C(sp3)–H cross-coupling reaction between sulfoximines and alkylarenes
作者:Qing-Ru Zhu, Peng-Zhan Zhang, Xiang Sun, Hui Gao, Pei-Long Wang*, Hongji Li*
单位:Key Laboratory of Green and Precise Synthetic Chemistry and Applications, Ministry of Education; School of Chemistry and Materials Science, Huaibei, Anhui 235000, PR China
摘要:An electrochemical oxidation-induced amination of simple alkylarenes with sulfoximines as a nitrogen source and 5,6-dimethyl-1Hbenzo[d]imidazole as a catalyst under mild conditions was developed. This protocol represents a rare example of benzylic C–H functionalization of alkylarenes that involves the electrochemical generation of N-center radical, providing access to a range of corresponding aminated products in moderate to good yields.
影响因子:9.3
分区情况:一区
链接:https://pubs.rsc.org/en/content/articlelanding/2024/gc/d4gc00191e
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